| September 13, 2020 | ||
| Barcelona | 01:00 | Elche |
| Real Madrid | 01:00 | Getafe |
| September 20, 2020 | ||
| Levante | 01:00 | Atlético de Madrid |
| Sevilla | 01:00 | Elche |
| November 28, 2020 | ||
| Elche | 15:00 | Cádiz |
| Valencia | 17:15 | Atlético de Madrid |
| Huesca | 19:30 | Sevilla |
| Real Madrid | 22:00 | Deportivo Alavés |
| November 29, 2020 | ||
| Barcelona | 15:00 | Osasuna |
| Getafe | 17:15 | Athletic Bilbao |
| Celta Vigo | 19:30 | Granada |
| Real Sociedad | 22:00 | Villarreal |
| November 30, 2020 | ||
| Real Betis | 22:00 | Eibar |
| December 4, 2020 | ||
| Athletic Bilbao | 22:00 | Celta Vigo |
| December 5, 2020 | ||
| Levante | 15:00 | Getafe |
| Sevilla | 17:15 | Real Madrid |
| Atlético de Madrid | 19:30 | Real Valladolid |
| Cádiz | 22:00 | Barcelona |
